Product ID:MANGANESE (II) SULFATE MONOHYDRATE, M113, M113500
MSDS Date:09/02/1997
FSC:NIIN:Submitter:N EN
Status Code:A
MSDS Number: CLNPT

Emergency Phone: 201-796-7100/703-527-3887

Info Phone: 201-796-7100

Cage: 1B464

Telephone: 201-796-7100

Cage: 1B464

UNLISTED;

CAS: 10034-96-5

RTECS: OP0893500

OSHA PEL SEE ABOVE

ACGIH TLV: NONE LISTED

LD50 LC50 Mixture:LD50/LC50: NOT AVAILABLE.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EMERGENCY OVERVIEW: APPEARANCE: PINK.
CAUTION! MAY CAUSE CENTRAL NERVOUS SYSTEM EFFECTS. MAY CAUSE EYE
AND SKIN IRRITATION. MAY CAUSE RESPIRATORY AND DIGESTIVE TRACT
IRRITATION. TARGET ORGANS: CENTRAL NERVOUS SYSTEM. POTENTIAL
HEALTH EFFECTS: EYE: MAY CAUSE MILD EYE IRRITATION. SKIN: MAY CAUSE
SKIN IRRITATION. LOW HAZARD FOR USUAL INDUSTRIAL HANDLING.
INGESTION: MAY CAUSE GASTROINTESTINAL IRRITATI ON WITH NAUSEA,
VOMITING AND DIARRHEA. INHALATION: MAY CAUSE RESPIRATORY TRACT
IRRITATION. CHRONIC: CHRONIC INHALATION OR INGESTION MAY CAUSE
ARGYRIA CHARACTERIZED BY BLUE-GRAY DISCOLORATION OF THE EY ES, SKIN
AND MUCOUS (OVEREXPOSURE)
Explanation of Carcinogenicity:CAS# 10034-96-5 NOT LISTED BY ACGIH,
IARC, NIOSH, NTP, OR OSHA.
Effects of Overexposure:HEALTH HAZARDS ACUTE AND CHRONIC (CONT'D):
MEMBRANES. CHRONIC SKIN CONTACT MAY CAUSE PERMANENT DISCOLORATION
OF THE SKIN.

First Aid:EYES: FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15
MINUTES, OCCASIONALLY LIFTING THE UPPER AND LOWER LIDS. GET MEDICAL
AID. SKIN: FLUSH SKIN WITH PLENTY OF SOAP AND WATER FOR AT LEAST 15
MINUTES WH ILE REMOVING CONTAMINATED CLOTHING AND SHOES. GET
MEDICAL AID IF IRRITATION DEVELOPS OR PERSISTS. INGESTION: IF
VICTIM IS CONSCIOUS AND ALERT, GIVE 2-4 CUPFULS OF MILK OR WATER.
NEVER GIVE ANYTHING B Y MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL
AID. INHALATION: REMOVE FROM EXPOSURE TO FRESH AIR IMMEDIATELY. IF
NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS
DIFFICULT, GIVE OXYGEN. NOT ES TO PHYSICIAN: TREAT (TOXICOLOGICAL)

Flash Point:NOT AVAILABLE
Extinguishing Media:FOR SMALL FIRES, USE WATER SPRAY, DRY CHEMICAL,
CARBON DIOXIDE OR CHEMICAL FOAM.
Fire Fighting Procedures:AS IN ANY FIRE, WEAR A SELF-CONTAINED
BREATHING APPARATUS IN PRESSURE-DEMAND, NIOSH APPROVED OR
EQUIVALENT AND FULL PROTECTIVE GEAR. MATERIAL WILL NOT BURN.
Unusual Fire/Explosion Hazard:N/P. HEALTH - 1, FLAMMABILITY - 0,
REACTIVITY - 0.

Spill Release Procedures:GENERAL INFORMATION: USE PROPER PERSONAL
PROTECTIVE EQUIPMENT AS INDICATED IN CONTROL MEASURES SECTION OF
THIS MSDS. VACUUM OR SWEEP UP MATERIAL AND PLACE INTO A SUITABLE
DISPOSAL CONTAINER. AVOID GEN ERATING DUSTY CONDITIONS.

Handling and Storage Precautions:HANDLING: WASH HANDS BEFORE EATING.
USE WITH ADEQUATE VENTILATION. AVOID CONTACT WITH SKIN AND EYES.
AVOID INGESTION AND INHALATION. STORAGE: STORE IN A TIGHTLY CLOSED
CONTAINER.

Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN
29CFR 1910.134 OR EUROPEAN STANDARD EN 149. ALWAYS USE A NIOSH OR
EUROPEAN STANDARD EN 149 APPROVED RESPIRATOR WHEN NECESSARY.
Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP
AIRBORNE CONCENTRATIONS BELOW THE PERMISSIBLE EXPOSURE LIMITS.
Protective Gloves:WEAR IMPERVIOUS GLOVES.
Eye Protection:WEAR APPROPRIATE PROTECTIVE EYEGLASSES OR CHEMICAL
SAFETY (SUPPLEMENTAL SAFETY)
Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . WEAR APPROPRIATE PROTECTIVE GLOVES AND CLOTHING
TO PREVENT SKIN EXPOSURE.
Work Hygienic Practices:WASH HANDS BEFORE EATING.
Supplemental Safety and Health
EYE PROTECTION (CONT'D): GOGGLES AS DESCRIBED BY OSHA'S EYE AND FACE
PROTECTION REGULATIONS IN 29 CFR 1910.133 OR EUROPEAN STANDARD
EN166. PHYSICAL/CHEMICAL (CON'T): MOLECULAR FORMULA: MNSO4.H2O. M
OLECULAR WEIGHT: N/P. SYNONYMS: MANGANESE (II) SULFATE,
MONOHYDRATE, MANGANOUS SULFATE MONOHYDRATE.

Boiling Pt:=850.C, 1562.F
Melt/Freeze Pt:=700.C, ######F
Decomp Temp:Decomp Text:NOT AVAILABLE
Vapor Pres:NOT AVAILABLE
Vapor Density:NA
Spec Gravity:3.25 (WATER=1)
pH:NOT AVAILABLE
Viscosity:NOT AVAILABLE
Solubility in Water:COMPLETE IN WATER
Appearance and Odor:PINK SOLID. ODORLESS.

Stability Indicator/Materials to Avoid:YES
CAN REACT WITH STRONG ACID, STRONG OXIDIZING AGENTS, POWDERED METALS;
MAY REACT VIOLENTLY WITH HYDROGEN PEROXIDE.
Stability Condition to Avoid:INCOMPATIBLE MATERIALS.
Hazardous Decomposition Products:CARBON DIOXIDE, SULFUR OXIDES (SOX),
INCLUDING SULFUR OXIDE AND SULFUR DIOXIDE, OXIDES OF MANGANESE.

Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
STATE AND LOCAL REGULATIONS. RCRA D-SERIES MAXIMUM CONCENTRATION OF
CONTAMINANTS: NONE LISTED. RCRA D-SERIES CHRONIC TOXICITY REFERENCE
LEVELS: NONE LIS TED. RCRA F-SERIES: NONE LISTED. RCRA P-SERIES:
NONE LISTED. RCRA U-SERIES: NONE LISTED.

Toxicological Information:RTECS#: CAS# 10034-96-5: OP0893500.
LD50/LC50: NOT AVAILABLE. EPIDEMIOLOGY: NO DATA AVAILABLE.
TERATOGENICITY: NO DATA AVAILABLE. REPRODUCTIVE EFFECTS: NO DATA
AVAILABLE. NEUROTOXICITY: NO DATA AVAIL ABLE. MUTAGENICITY: NO
DATA AVAILABLE. OTHER STUDIES: NO DATA AVAILABLE. FOR FOREIGN
COUNTRIES OCCUPATIONAL EXPOSURE LIMITS (OEL), CONTACT NEHC . FIRST
AID (CON'T): SUPPORTIVELY. ANTIDOTE: TH E USE OF CALCIUM DISODIUM
EDTA AS A CHELATING AGENT SHOULD BE DETERMINED BY QUALIFIED MEDICAL
PERSONNEL.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:ECOTOXICITY: NOT AVAILABLE. ENVIRONMENTAL FATE: NOT
AVAILABLE. PHYSICAL/CHEMICAL: NOT AVAILABLE. OTHER: NOT AVAILABLE.

Transport Information:SHIPPING NAME, HAZARD CLASS, UN NUMBER, PACKING
GROUP UNDER US DOT, IATA, RID/ADR, IMO AND CANADA TDG: NO
INFORMATION AVAILABLE.

SARA Title III Information:SECTION 302 (RQ), (TPQ): NO CHEMICAL IN THIS
MATERIAL HAS AN RQ OR TPQ. SARA CODES: CAS# 10034-96-5: CHRONIC.
SECTION 313: MATERIAL CONTAINS MANGANESE SULFATE, MONOHYDRATE
(LISTED AS MANGANESE), 98% ( CAS# 10034-96-5) WHICH IS SUBJECT TO
THE REPORTING REQUIREMENTS OF SECTION 313 OF SARA TITLE III AND 40
CFR PART 373.
Federal Regulatory Information:CAS#10034-96-5 IS NOT ON THE TSCA
INVENTORY. IT IS A HYDRATE & EXEMPT FROM TSCA INVENTORY
REQUIREMENTS (40CFR720.3(U) (2)). HEALTH & SAFETY REPORTING LIST:
NONE OF THE CHEMICALS ARE ON THIS LIST. CHEM ICAL TEST RULES: NONE
OF THE CHEMICALS IN THIS PRODUCT ARE UNDER A CHEMICAL TEST RULE.
SECTION 12B: NONE OF THE CHEMICALS ARE LISTED UNDER TSCA SECTION
12B. TSCA SIGNIFICANT NEW USE RULE: NONE OF THE CHEMICALS IN THIS
MATERIAL HAVE A SNUR UNDER TSCA. OSHA: NONE OF THE CHEMICALS IN
THIS PRODUCT ARE C ONSIDERED HIGHLY HAZARDOUS BY OSHA. CLEAN AIR
ACT: THIS MATERIAL DOES NOT CONTAIN ANY HAZARDOUS AIR POLLUTANTS.
THIS MATERIAL DOES (STATE)
State Regulatory Information:CAS# 10034-96-5 IS NOT PRESENT ON STATE
LISTS FROM CA, PA, MN, MA, FL, OR NJ. CALIFORNIA NO SIGNIFICANT
RISK LEVEL: NONE OF THE CHEMICALS IN THIS PRODUCT ARE LISTED.
FEDERAL REGS (CON'T): NOT CONTAIN ANY CLASS 1 OZONE DEPLETORS.
THIS MATERIAL DOES NOT CONTAIN ANY CLASS 2 OZONE DEPLETORS. CLEAN
WATER ACT: NONE OF THE CHEMICALS IN THIS PRODUCT ARE LISTED AS
HAZARDOUS SUBSTANCES UNDER THE CWA. NONE OF THE CHEMICALS IN THIS
PRODUCT ARE LISTED AS PRIORITY POLLUTANTS UNDER THE CWA. NONE OF
THE CHEMIC ALS IN THIS PRODUCT ARE LISTED AS TOXIC POLLUTANTS UNDER
THE CWA. EUROPEAN/INTERNATIONAL REGULATIONS: EUROPEAN LABELING
(OTHER INFORMATION)